Lesson 1 of 2

Energy and Systems

Define thermodynamic systems, boundaries, and forms of energy.

Systems and surroundings

In thermodynamics we analyze a system - the part of the universe we care about - separated from its surroundings by a boundary. Systems can be:

  • Closed - no mass crosses the boundary (but energy can).
  • Open - both mass and energy can cross (a control volume).
  • Isolated - neither mass nor energy crosses.

Forms of energy

Energy shows up in many forms:

  • Internal energy (U) - the microscopic energy of molecules.
  • Kinetic energy - energy of motion.
  • Potential energy - energy of position.
  • Heat (Q) - energy transferred due to temperature difference.
  • Work (W) - energy transferred by a force acting through a distance.

Why it matters

Correctly defining your system and identifying energy flows is the first step in every thermodynamics problem. Get this right and the equations follow naturally.